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Beilstein J. Org. Chem. 2013, 9, 2387–2394, doi:10.3762/bjoc.9.275
Graphical Abstract
Figure 1: Example of bioactive molecules bearing the 2-isoxazoline nucleus.
Scheme 1: Synthesis of 3-trifluoromethyl-2-isoxazolines.
Scheme 2: Synthesis of aldoxime 2.
Figure 2: Dimerization and isomerization products from nitrile oxides.
Figure 3: Dimerization of 4 yielding bis(trifluoromethyl)furoxan 6.
Figure 4: Depiction of the geometry (left column) and isodensity surface of the reacting frontier molecular o...
Figure 5: FMO energy levels of dipole 4 and dipolarophiles 5a and 5k calculated at the B3LYP/6-31G* level. Co...
Figure 6: Yields of the cycloaddition reaction plotted against the HOMO energy levels of the dipolarophile pa...